Liquid Phase Hydrogenation of MIBK over M/CsPW (M = Ag, Ru, Pt, and Pd)

Autor:	Abdullah M. Alhanash, Amal A. Atran, Murad Eissa, Mhamed Benaissa, Mohamed S. Hamdy
Jazyk:	angličtina
Rok vydání:	2019
Předmět:	heterogeneous catalysis MIBK conversion solvent-free hydrogenation 2-methylpentane CsPW MIBC Chemical technology TP1-1185 Chemistry QD1-999
Zdroj:	Catalysts, Vol 9, Iss 1, p 47 (2019)
Druh dokumentu:	article
ISSN:	2073-4344
DOI:	10.3390/catal9010047
Popis:	Four different metal nanoparticles (metal = Ag, Ru, Pt, or Rh) were impregnated on the acidic cesium salt of tungstophosphoric acid Cs2.5H0.5PW12O40 (CsPW) with a loading amount of 2 wt%. The prepared catalysts were characterized by using X-ray diffraction (XRD), Fourier transform-infrared spectroscopy (FTIR), N2 sorption measurements, scanning electron microscopy (SEM), and energy-dispersive X-ray spectroscopy (EDX). Results confirmed the formation of highly distributed metallic nanoparticle centres over the acidic CsPW. The catalytic activity of the prepared catalysts were evaluated in the liquid phase hydrogenation of methyl isobutyl ketone (MIBK) to 2-methylpentane (2-MP) at 453 K. Pd-CsPW showed the highest activity compared to other catalysts, where 10% conversion was obtained with 91% selectivity after 4 h’s reaction time.
Databáze:	Directory of Open Access Journals
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