Ultralong afterglow and unity quantum yield from a transparent CsCdCl3:Mn crystal

Autor: Yeqi Liu, Xiangzhou Zhang, Xiaojia Wang, Shao Yan, Yanjie Liang, Yuhai Zhang
Jazyk: angličtina
Rok vydání: 2023
Předmět:
Zdroj: Aggregate, Vol 4, Iss 4, Pp n/a-n/a (2023)
Druh dokumentu: article
ISSN: 2692-4560
DOI: 10.1002/agt2.334
Popis: Abstract Transparent afterglow crystals are keenly desired for three‐dimensional information storage. Herein, CsCdCl3 perovskite crystals were grown by a programmable cooling procedure in a hydrothermal reactor. The pristine crystal showed an abnormal optical behavior where the absorption increased by 2.3 folds at high temperature, leading to a fourfold boost of photoluminescence (PL) intensity. After Mn2+ doping, the PL quantum yield was improved to nearly unity. Importantly, the doped crystals exhibited an ultralong afterglow up to 12 h after ceasing UV excitation and a high transmittance up to 75% in the visible region. This work brought a new member to the library of transparent afterglow crystal, opening up many possibilities to advanced applications such as volumetric display and three‐dimensional information encryption.
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