REFLECTANCE UV-VIS AND UV RESONANCE RAMAN SPECTROSCOPY IN CHARACTERIZATION OF KRAFT PULPS

Autor: Anni Lähdetie, Tiina Liitiä, Tarja Tamminen, Anna-Stiina Jääskeläinen
Jazyk: angličtina
Rok vydání: 2009
Předmět:
Zdroj: BioResources, Vol 4, Iss 4, Pp 1600-1619 (2009)
Druh dokumentu: article
ISSN: 1930-2126
Popis: Reflectance UV-Vis spectroscopy and UV resonance Raman (UVRR) spectroscopy are both nondestructive techniques that are applicable to study trace concentrations of lignin in-situ. In this study, unbleached and bleached softwood kraft pulps were analyzed by reflectance UV-Vis (k/s) and UVRR spectroscopy to follow lignin and hexenuronic acid (HexA) contents and structural changes in residual lignin. The height of the lignin band in the UV-Vis spectra (280 nm) correlated well with the lignin band in the UVRR spectra (1605 cm-1) for semi- or fully-bleached pulps. However, the correlation was much weaker for unbleached pulps. Also the results for hexenuronic acid content by UV-Vis (240 nm) and UVRR (1658 cm-1) methods correlated well for most of the pulps, but for unbleached or peroxide-bleached samples the interference from other structures affecting these bands was obvious.
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