Tetrakis(acetonitrile)copper(I) hydrogen oxalate–oxalic acid–acetonitrile (1/0.5/0.5)
| Autor: | A. Timothy Royappa, Jacob R. Stepherson, Oliver D. Vu, Andrew D. Royappa, Charlotte L. Stern, Peter Müller |
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| Jazyk: | angličtina |
| Rok vydání: | 2013 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 69, Iss 10, Pp m544-m544 (2013) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536813024914 |
| Popis: | In the title compound, [Cu(CH3CN)4](C2HO4)·0.5C2H2O4·0.5CH3CN, the CuI ion is coordinated by the N atoms of four acetonitrile ligands in a slightly distorted tetrahedral environment. The oxalic acid molecule lies across an inversion center. The acetonitrile solvent molecule is disordered across an inversion center and was refined with half occupancy. In the crystal, the hydrogen oxalate anions and oxalic acid molecules are linked via O—H...O hydrogen bonds, forming chains along [010]. |
| Databáze: | Directory of Open Access Journals |
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