Sugarcane Bagasse Hydrolysis Enhancement by Microwave-Assisted Sulfolane Pretreatment

Autor: Patricia Portero-Barahona, Enrique Javier Carvajal-Barriga, Jesús Martín-Gil, Pablo Martín-Ramos
Jazyk: angličtina
Rok vydání: 2019
Předmět:
Zdroj: Energies, Vol 12, Iss 9, p 1703 (2019)
Druh dokumentu: article
ISSN: 1996-1073
DOI: 10.3390/en12091703
Popis: Sugarcane bagasse is the major by-product of the sugarcane industry and, due to its abundant availability, it has been extensively studied for lignocellulosic bioconversion in the production of bioethanol and other value-added commercial products. In the study presented herein, a combined pretreatment using sulfolane, TiO2 and alkali microwave irradiation (MW-A) was assessed for the dissolution of lignin prior to enzymatic saccharification of holocellulose. Total reducing sugars (TRS) and saccharinic acid yields were investigated. The increase in NaOH concentration up to 5% and in temperature from 120 °C to 140 °C were found to have a positive influence on both yields. While increasing the reaction time from 5 to 60 min only led to an increase in TRS yield 2 reaction medium was used, as compared to MW-A in water, reaching up to 64.8% and 15.24 g/L of saccharinic acids, respectively. The proposed MW-A pretreatment may hold promise for industrial applications, given the good TRS yields obtained, and the associated enzyme and time/energy savings. The use of sulfolane-TiO2 reaction medium is encouraged if saccharinic acids are to be recovered too.
Databáze: Directory of Open Access Journals
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