| Autor: |
Ghobad Mansouri, Behroz Notash, Sami Sajadifar |
| Jazyk: |
English<br />Persian |
| Rok vydání: |
2019 |
| Předmět: |
|
| Zdroj: |
شیمی کاربردی روز, Vol 14, Iss 51, Pp 287-296 (2019) |
| Druh dokumentu: |
article |
| ISSN: |
2981-2437 |
| DOI: |
10.22075/chem.2019.15485.1490 |
| Popis: |
The Rh(III) complex[Rh(py)2(CH3CN)Cl3], Where py is pyridine has been prepared and characterized by elemental analysis, IR, and electronic absorption spectroscopies, and X-ray crystallography. The crystal structure of [Rh(py)2(CH3CN)Cl3] shows that the coordination geometry around the Rh(III) is a distorted octahedron. The title complex crystallized in monoclinic, space group P21/c, Z = 4, a = 7.626 (15) Å, b= 27.525(6) Å, c= 7.712 (15) Å and β=14.07(3)°. Electronic spectrum of the complex show that ligand – centered ( LCT ) transitions and metal- to- ligand charge transfer ( MLCT ). The molecular modeling of the complex was studied using a theoretical method and there was a good agreement between the results of the theory and the results of X-ray diffraction. Antibacterial activity of the complex has also been studied against Gram-positive bacteria (Staphylococcus aureus and Bacillus cereus ) and Gram-negative bacteria ( Pseudomunas aeroginosa and Escherichia coli). |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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