| Autor: |
Amira Zaouak, Fatma Matoussi, Mohamed Dachraoui |
| Jazyk: |
angličtina |
| Rok vydání: |
2011 |
| Předmět: |
|
| Zdroj: |
International Journal of Electrochemistry, Vol 2011 (2011) |
| Druh dokumentu: |
article |
| ISSN: |
2090-3537 |
| DOI: |
10.4061/2011/904570 |
| Popis: |
The electrochemical behaviour of five nitro diphenyl ethers used as herbicides is investigated in acetonitrile. A detailed study by cyclic voltammetry and exhaustive electrolysis is carried out for the anodic oxidation of 2-Chloro-6-nitro-3-phenoxyaniline (aclonifen) and shows that the major oxidation product is a dimeric compound. A mechanistic scheme involving a coupling process is postulated for the electrochemical oxidation of this compound. Furthermore, the use of differential pulse voltammetry on a glassy carbon electrode permits the selective determination of aclonifen. The limit of detection is 0.6 μg/mL. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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