catena-Poly[silver(I)-μ-acridine-9-carboxylato-κ3N:O,O′]

Autor: Ya-Qing Yang, Xiao-Ye Chen, Shu-Min Huo, Yan-Ru Ma, Rong-Hua Zeng
Jazyk: angličtina
Rok vydání: 2010
Předmět:
Zdroj: Acta Crystallographica Section E, Vol 66, Iss 11, Pp m1482-m1482 (2010)
Druh dokumentu: article
ISSN: 16005368
1600-5368
DOI: 10.1107/S1600536810043199
Popis: In the title coordination polymer, [Ag(C14H8NO2)]n, the AgI cation is coordinated by two O atoms and one N atom from two symmetry-related acridine-9-carboxylate ligands in a distorted trigonal-planar geometry. The metal atoms are connected by the ligands to form chains running parallel to the b axis. π–π stacking interactions [centroid-to-centroid distances 3.757 (2)–3.820 (2) Å] and weak Ag...O interactions further link the chains to form a layer network parallel to the ab plane. The AgI cation is disordered over two positions, with refined site-occupancy factors of 0.73 (3):0.27 (3).
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