trans-Diaquabis(N,N,N′-trimethylethylenediamine)nickel(II) dichloride
| Autor: | John R. Miecznikowski, Jerry P. Jasinski, Nicole F. Flaherty, Emma E. Mircovich, Allison N. Smolinsky, Natalia R. Bertolotti |
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| Jazyk: | angličtina |
| Rok vydání: | 2020 |
| Předmět: | |
| Zdroj: | IUCrData, Vol 5, Iss 9, p x201182 (2020) |
| Druh dokumentu: | article |
| ISSN: | 2414-3146 24143146 |
| DOI: | 10.1107/S2414314620011827 |
| Popis: | In the title salt, [Ni(C5H12N2)2(H2O)2]Cl2, the asymmetric unit is comprised of half of the complex cation and a chloride ion with the NiII atom of the cation situated about a twofold rotation axis. The six-coordinate NiII atom of the cation is connected to four N atoms from two methyl-substituted ethyelenediamine ligands and two water molecules in a slightly distorted octahedral environment. The five-membered chelate ring is in a slight envelope conformation. The crystal packing features O—H...Cl and N—H...Cl intermolecular interactions with the Cl− ion forming weak bifurcated hydrogen bonds with nearby water molecules and N—H interactions, leading to a three-dimensional supramolecular network structure. |
| Databáze: | Directory of Open Access Journals |
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