Popis: |
Biomass gasification is a favourable process to produce a H2-rich fuel gas from biogenic waste materials. In particular, the dual bubbling fluidized bed (DBFB) technology consists of the separation of the combustion chamber, fed with air, from the gasification chamber, fed with steam, allowing to obtain a concentrated syngas stream without N2 dilution. In a previous work, an innovative design of a DBFB reactor was developed and its hydrodynamics tested in a cold model; in this work, the novel gasifier was realized at pilot scale (100 kWth) and operated for preliminary biomass gasification tests. The results showed a high-quality syngas, composed of H2 = 35%, CO = 23%, CO2 = 20%, and CH4 = 11%, as a confirmation of the design efficacy in the separation of the reaction chambers. The dry gas yield obtained was 1.33 Nm3/kg of biomass feedstock and the carbon conversion was 73%. Tars were sampled and measured both in the raw syngas, giving a content of 12 g/Nm3, and downstream from a traditional conditioning system composed of a cyclone and a water scrubber, showing a residual tar content of 3 g/Nm3, mainly toluene. The preliminary tests showed promising results; further gasification tests are foreseen to optimize the main process parameters. |