Furfural Production from d-Xylose and Xylan by Using Stable Nafion NR50 and NaCl in a Microwave-Assisted Biphasic Reaction
| Autor: | Sarah Le Guenic, David Gergela, Claire Ceballos, Frederic Delbecq, Christophe Len |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2016 |
| Předmět: |
furfural
xylan Nafion NR50 biphasic system microwave-assisted dehydration Organic chemistry QD241-441 |
| Zdroj: | Molecules, Vol 21, Iss 8, p 1102 (2016) |
| Druh dokumentu: | article |
| ISSN: | 1420-3049 |
| DOI: | 10.3390/molecules21081102 |
| Popis: | Pentose dehydration and direct transformation of xylan into furfural were performed in a water-cyclopentyl methyl ether (CPME) biphasic system under microwave irradiation. Heated up between 170 and 190 °C in the presence of Nafion NR50 and NaCl, d-xylose, l-arabinose and xylan gave furfural with maximum yields of 80%, 42% and 55%, respectively. The influence of temperature and reaction time on the reaction kinetics was discussed. This study was also completed by the survey of different reactant ratios, such as organic layer-water or catalyst-inorganic salt ratios. The exchange between proton and cation induced by an excess of NaCl was monitored, and a synergetic effect between the remaining protons and the released HCl was also discovered. |
| Databáze: | Directory of Open Access Journals |
| Externí odkaz: |
|