Surface Structure Analysis of Initial High-Temperature Oxidation of SS441 Stainless Steel

Autor: Tung-Yuan Yung, Hui-Ping Tseng, Wen-Feng Lu, Kun-Chao Tsai, Tien Shen, Hsin-Ming Cheng, Jeng-Shiung Chen, Po-Tuan Chen
Jazyk: angličtina
Rok vydání: 2021
Předmět:
Zdroj: Materials, Vol 14, Iss 20, p 6136 (2021)
Druh dokumentu: article
ISSN: 1996-1944
DOI: 10.3390/ma14206136
Popis: Chromia-forming ferritic stainless steel (FSS) is a highly promising interconnect material for application in solid oxide fuel cells. In this study, initial oxidation of chromium oxides was performed at 500–800 °C to understand the evolution of materials at an early stage. The structural variations in oxide scales were analyzed through scanning electron microscopy, energy dispersive spectroscopy (EDS), transmission electron microscopy (TEM), X-ray diffractometry (XRD), laser confocal microscopy (LSCM), X-ray photoelectron spectroscopy (XPS), and Raman spectroscopy. Surface electrochemical properties were investigated through electrochemical impedance spectroscopy to understand how the heat treatment temperature affected surface impedance. Treatment temperatures higher than 700 °C facilitate the diffusion of Cr and Mn, thus allowing ferritic spinels to form on the surface and leading to high electrical conductivity.
Databáze: Directory of Open Access Journals