Benzyl 2-methyl-3-[(E)-(thiophen-2-yl)methylidene]dithiocarbazate

Autor: Saroj K. S. Hazari, B. K. Dey, Tapashi G. Roy, B. Ganguly, Seik Weng Ng, Edward R. T. Tiekink
Jazyk: angličtina
Rok vydání: 2012
Předmět:
Zdroj: Acta Crystallographica Section E, Vol 68, Iss 4, Pp o1216-o1216 (2012)
Druh dokumentu: article
ISSN: 16005368
1600-5368
DOI: 10.1107/S1600536812012652
Popis: In the title compound, C14H14N2S3, the thione S atom and methyl group are syn, as are the two thioether S atoms. The molecule is twisted, the dihedral angles between the central (C2N2S2) residue and the pendent 2-thienyl and phenyl rings being 21.57 (6) and 77.54 (3)°, respectively. In the crystal, molecules assemble into a three-dimensional architecture via C—H...π interactions, involving both the five- and six-membered rings as acceptors, as well as S...S interactions [3.3406 (5) Å] between centrosymmetrically related 2-thienyl rings.
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