catena-Poly[[[diaqua(1,10-phenanthroline-κ2N,N′)zinc]-μ-4,4′-bipyridine-κ2N:N′] dinitrate 4,4′-bipyridine hemisolvate monohydrate]
| Autor: | Shan Xu, Yong-Cheng Dai, Qi-Ming Qiu, Qiong-Hua Jin, Cun-Lin Zhang |
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| Jazyk: | angličtina |
| Rok vydání: | 2012 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 68, Iss 9, Pp m1222-m1223 (2012) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536812036318 |
| Popis: | In the title compound, [Zn(C10H8N2)(C12H8N2)(H2O)2](NO3)2·0.5C10H8N2·H2O, the ZnII atom is coordinated in a distorted octahedral geometry by two N atoms from two 4,4′-bipyridine (4,4′-bipy) ligands, two N atoms from a chelating 1,10-phenanthroline ligand and two O atoms from two mutually cis water molecules. The 4,4′-bipy ligands bridge the ZnII atoms into a chain structure along [100]. The uncoordinated 4,4′-bipy molecule lies on an inversion center. O—H...O and O—H...N hydrogen bonds connect the cationic chains, the nitrate anions, the uncoordinated 4,4′-bipy molecules and the water molecules into tow-dimensional networks. |
| Databáze: | Directory of Open Access Journals |
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