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Abstract To protect a canvas easel painting, a common conservation strategy is to add a back plate at the stretcher, creating a closed air void. This plate protects not only from dust but mainly from temperature and relative humidity (RH) variations in the room and moisture changes in the wall on which it is hanging. The addition of hygroscopic layers can reduce the amplitude and change phase of humidity oscillations. This paper proposes a new mathematical model that can be used to predict moisture levels within the canvas when this conservation strategy is applied. The model is compared against the temperature and RH detailed experimental data, captured and shown in the latest paper by Padfield et al. Back protection of canvas painting. Our paper presents values of T, RH and mixing ratio (MR) obtained at the different layers of an easel painting, protected and unprotected, with cotton and without it, submitted to different room and wall temperature and RH cycles. The experimental results show a phase displacement between the canvas temperatures and the corresponding RH values in the canvas air boundary layer. In some cases this phase shift, which is an unexpected behaviour, allows RH and temperatures to achieve their maximum value at the same time. The purpose of the model is to simulate the RH response at the different air boundary layers inside the air void, such as the canvas, the aluminium back plate, and the hygroscopic cotton protection, produced by cyclic variations of temperature in the room or the wall. The model is built simulating four interrelated processes: the canvas permeation flow, the air infiltration rate between room and void, the equilibrium moisture content (EMC) and the vapour sorption rate for the canvas and the cotton. A key innovation of the model is the dependence between EMC, sorption rate, and RH condition, which captures the counter-intuitive behaviours observed in the data. The model results agree with the experimental results. The developed tool allows the interpretation of the processes involved and to extend the simulations to other cases, materials, and conditions. |
