Autor: |
Chi M. Phan, Son A. Hoang, Son H. Vu, Hoang M. Nguyen, Cuong V. Nguyen, Anita E. Hyde, Shin-ichi Yusa |
Jazyk: |
angličtina |
Rok vydání: |
2021 |
Předmět: |
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Zdroj: |
Chemical and Biological Technologies in Agriculture, Vol 8, Iss 1, Pp 1-7 (2021) |
Druh dokumentu: |
article |
ISSN: |
2196-5641 |
DOI: |
10.1186/s40538-021-00236-5 |
Popis: |
Abstract Background Cashew nut shell is a by-product of cashew (Anacardium occidentale) production, which is abundant in many developing countries. Cashew nut shell liquor (CNSL) contains a functional chemical, cardanol, which can be converted into a hydroxyoxime. The hydroxyoximes are expensive reagents for metal extraction. Methods CNSL-based oxime was synthesized and used to extract Ni, Co, and Mn from aqueous solutions. The extraction potential was compared against a commercial extractant (LIX 860N). Results All metals were successfully extracted with pH0.5 between 4 and 6. The loaded organic phase was subsequently stripped with an acidic solution. The extraction efficiency and pH0.5 of the CNSL-based extractant were similar to a commercial phenol-oxime extractant. The metals were stripped from the loaded organic phase with a recovery rate of 95% at a pH of 1. Conclusions Cashew-based cardanol can be used to economically produce an oxime in a simple process. The naturally-based oxime has the economic potential to sustainably recover valuable metals from spent lithium-ion batteries. Graphic abstract |
Databáze: |
Directory of Open Access Journals |
Externí odkaz: |
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