Waste bio-tar based N-doped porous carbon for supercapacitors under dual activation: performance, mechanism, and assessment

Autor: Jixiu Jia, Yuxuan Sun, Zhidan Liu, Ziyun Liu, Lili Huo, Kang Kang, Yanan Zhao, Lixin Zhao, Teng Xie, Maojiong Cao, Zonglu Yao
Jazyk: angličtina
Rok vydání: 2023
Předmět:
Zdroj: Biochar, Vol 5, Iss 1, Pp 1-15 (2023)
Druh dokumentu: article
ISSN: 2524-7867
DOI: 10.1007/s42773-023-00293-z
Popis: Abstract Bio-tar extra-produced from biomass pyrolysis is prone to pose a threat to environment and human health. A novel N-doped porous electrode from bio-tar was produced under dual-activation of urea and KOH in this study. One-pot dual-activation played significant roles in N-functional group and micro-mesoporous structure, which resulted in the carbon material with the highest of nitrogen content (4.08%) and the special surface area (1298.26 m2·g−1). Specifically, the potential mechanisms of pore formation and N-doping in the one-pot dual-activation strategy were also proposed as a consequence, the one-pot dual-activated carbon material displayed excellent electrochemical performance with the highest capacitance of 309.5 F·g−1 at 0.5 A·g−1, and the unipolar specific capacitance remained with cyclic characteristics of 80.1% after 10,000 cycles in two-electrode symmetric system. Furthermore, the one-pot dual-activation strategy could create a profit of $1.64–$2.38 per kilogram of bio-tar processed without considering the initial investment and labor costs, which provides new perspectives for the utilization of waste bio-tar. Graphical Abstract
Databáze: Directory of Open Access Journals
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