| Autor: |
Yingyan Zhao, Zhibing Liu, Jiangchuan Liu, Yunfeng Zhu, Jiguang Zhang, Yana Liu, Xiaohui Hu, Liquan Li |
| Jazyk: |
angličtina |
| Rok vydání: |
2024 |
| Předmět: |
|
| Zdroj: |
Journal of Magnesium and Alloys, Vol 12, Iss 1, Pp 197-208 (2024) |
| Druh dokumentu: |
article |
| ISSN: |
2213-9567 |
| DOI: |
10.1016/j.jma.2022.04.006 |
| Popis: |
The hydrogen absorption/desorption kinetic properties of MgH2 can be effectively enhanced by doping specific catalysts. In this work, MOFs-derived NiCu@C nanoparticles (∼15 nm) with regular core-shell structure were successfully prepared and introduced into MgH2 (denoted as MgH2NiCu@C). The onset and peak temperatures of hydrogen desorption of MgH2–11 wt.% NiCu@C are 175.0 °C and 282.2 °C, respectively. The apparent activation energy of dehydrogenated reaction is 77.2 ± 4.5 kJ/mol for MgH2–11 wt.% NiCu@C, which is lower than half of that of the as-milled MgH2. Moreover, MgH2–11 wt.% NiCu@C displays great cyclic stability. The strengthening “hydrogen pumping” effect of reversible solid solutions Mg2Ni(Cu)/Mg2Ni(Cu)H4 is proposed to explain the remarkable improvement in hydrogen absorption/desorption kinetic properties of MgH2. This work offers a novel perspective for the design of bimetallic nanoparticles and beyond for application in hydrogen storage and other energy related fields. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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