The crystal structure of Iridium Complex with Thiocarbamide
| Autor: | T. M. Buslaeva, E. V. Kopylova, V. V. Kravchenko, G. A. Fedorova |
|---|---|
| Jazyk: | ruština |
| Rok vydání: | 2008 |
| Předmět: | |
| Zdroj: | Тонкие химические технологии, Vol 3, Iss 5, Pp 57-61 (2008) |
| Druh dokumentu: | article |
| ISSN: | 2410-6593 2686-7575 |
| Popis: | By interaction of water solutions of K3[IrCl6] and Thiocarbamide (Thio, SC(NH2)2) at heating the complex of the composition [Ir(Thio)3Cl3] was synthesized. By the method of X-ray diffraction that the compound crystallizes in the monoclinic crystal system with space group C2/c, a = 13.492(3) Å, b = 8.264(2) Å, c = 24.979(5) Å, β = 92.79(3), V = 2782.00(1) Å3 , Z = 8. The compound has a structure with two crystallographically independent iridium atoms: the coordination sphere of the Ir(1) atom involves two Cl atoms and four S atom, whereas the coordination sphere of the Ir(2) atom consists four Cl atoms and two S atom. Coordination of molecules Thio to the Iridium is realized though the sulfur atom. |
| Databáze: | Directory of Open Access Journals |
| Externí odkaz: |
|