| Autor: |
Ignacio Bernabé Vírseda, Arthur Mantel, Alexander Prado-Roller, Michael Eisterer, Hidetsugu Shiozawa |
| Jazyk: |
angličtina |
| Rok vydání: |
2023 |
| Předmět: |
|
| Zdroj: |
Royal Society Open Science, Vol 10, Iss 11 (2023) |
| Druh dokumentu: |
article |
| ISSN: |
2054-5703 |
| DOI: |
10.1098/rsos.230910 |
| Popis: |
A coordination polymer of linear trimeric cobalt units and melamine has been synthesized. The magnetic isotherms of violet coloured crystals as long as 400 μm show a field-induced transition in an external field of about 2 T at temperatures approximately below 2 K. It is addressed that by assuming the coexistent positive and negative exchange between the nearest-neighbour spins in the linear trimer, this metamagnetism can be interpreted as a transition from antiferromagnetic to ferromagnetic exchange within each trimeric spin cluster. Although weak inter-cluster or inter-chain exchange to yield a long-range magnetic order is another possible and often attributed origin of metamagnetism in low-dimensional spin systems, this study demonstrates the significance of the exchange flip within each cluster in clustered spin networks. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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