Aquabis[1-hydroxy-2-(imidazol-3-ium-1-yl)-1,1′-ethylidenediphophonato-κ2O,O′]zinc(II) dihydrate
| Autor: | Eleonora Freire, Daniel R. Vega |
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| Jazyk: | angličtina |
| Rok vydání: | 2009 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 65, Iss 11, Pp m1430-m1431 (2009) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S160053680904286X |
| Popis: | In the title complex, [Zn(C5H9NO7P2)2(H2O)]·2H2O, the zinc atom is coordinated by two zoledronate anions [zoledronate = (2-(1-imidazole)-1-hydroxy-1,1′-ethylidenediphophonate)] and one water molecule. The coordination number is 5. There is one half-molecule in the asymmetric unit, the zinc atom being located on a twofold rotation axis passing through the metal centre and the coordinating water O atom. The anion exists as a zwitterion with an overall charge of −1; the protonated nitrogen in the ring has a positive charge and the two phosphonates groups each have a single negative charge. Intermolecular O—H...O hydrogen bonds link the molecules. An N—H...O interaction is also present. |
| Databáze: | Directory of Open Access Journals |
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