| Autor: |
Andrea Brognara, Ankush Kashiwar, Chanwon Jung, Xukai Zhang, Ali Ahmadian, Nicolas Gauquelin, Johan Verbeeck, Philippe Djemia, Damien Faurie, Gerhard Dehm, Hosni Idrissi, James Paul Best, Matteo Ghidelli |
| Jazyk: |
angličtina |
| Rok vydání: |
2024 |
| Předmět: |
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| Zdroj: |
Small Structures, Vol 5, Iss 9, Pp n/a-n/a (2024) |
| Druh dokumentu: |
article |
| ISSN: |
2688-4062 |
| DOI: |
10.1002/sstr.202400011 |
| Popis: |
The design of high‐performance structural thin films consistently seeks to achieve a delicate equilibrium by balancing outstanding mechanical properties like yield strength, ductility, and substrate adhesion, which are often mutually exclusive. Metallic glasses (MGs) with their amorphous structure have superior strength, but usually poor ductility with catastrophic failure induced by shear bands (SBs) formation. Herein, we introduce an innovative approach by synthesizing MGs characterized by large and tunable mechanical properties, pioneering a nanoengineering design based on the control of nanoscale chemical/structural heterogeneities. This is realized through a simplified model Zr24Cu76/Zr61Cu39, fully amorphous nanocomposite with controlled nanoscale periodicity (Λ, from 400 down to 5 nm), local chemistry, and glass–glass interfaces, while focusing in‐depth on the SB nucleation/propagation processes. The nanolaminates enable a fine control of the mechanical properties, and an onset of crack formation/percolation (>1.9 and 3.3%, respectively) far above the monolithic counterparts. Moreover, we show that SB propagation induces large chemical intermixing, enabling a brittle‐to‐ductile transition when Λ ≤ 50 nm, reaching remarkably large plastic deformation of 16% in compression and yield strength ≈2 GPa. Overall, the nanoengineered control of local heterogeneities leads to ultimate and tunable mechanical properties opening up a new approach for strong and ductile materials. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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