Ultrafine-Grained Magnesium Alloys for Hydrogen Storage Obtained by Severe Plastic Deformation

Autor: Eugen Rabkin, Vladimir Skripnyuk, Yuri Estrin
Jazyk: angličtina
Rok vydání: 2019
Předmět:
Zdroj: Frontiers in Materials, Vol 6 (2019)
Druh dokumentu: article
ISSN: 2296-8016
DOI: 10.3389/fmats.2019.00240
Popis: Magnesium alloys take a special place among the hydrogen storage materials, mainly due to their high gravimetric (7.6 mass %) and volumetric (110 kg m−3) hydrogen storage capacity. Unfortunately, the kinetics of hydrogenation and hydrogen release are rather slow, which limits practical use of magnesium-based materials for hydrogen and heat storage. Refining the microstructure of magnesium alloys, ideally down to nanoscale, is known to accelerate the hydrogenation/dehydrogenation kinetics. A possible way to achieve that is by severe plastic deformation. Our first demonstration of this effect through processing of a Mg alloy (ZK60) by equal-channel angular pressing prompted a stream of further studies employing severe plastic deformation techniques to improve the hydrogen storage-relevant properties of Mg alloys. The present article provides an overview of the literature on the subject, with a natural focus on our own data.
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