Enhanced Ionic Accessibility of Flexible MXene Electrodes Produced by Natural Sedimentation

Autor: Ning Sun, Zhaoruxin Guan, Qizhen Zhu, Babak Anasori, Yury Gogotsi, Bin Xu
Jazyk: angličtina
Rok vydání: 2020
Předmět:
Zdroj: Nano-Micro Letters, Vol 12, Iss 1, Pp 1-11 (2020)
Druh dokumentu: article
ISSN: 2311-6706
2150-5551
DOI: 10.1007/s40820-020-00426-0
Popis: Abstract MXene nanosheets have been used for preparing highly flexible integrated electrodes due to their two-dimensional (2D) morphology, flexibility, high conductivity, and abundant functional groups. However, restacking of 2D nanosheets inhibits the ion transport in MXene electrodes, limiting their thickness, rate performance, and energy storage capacity. Here, we employed a natural sedimentation method instead of the conventional vacuum-assisted filtration to prepare flexible Ti3C2T x MXene films with enlarged interlayer spacing, which facilitates the access of the lithium ions to the interlayers and thus leads to a greatly enhanced electrochemical performance. The naturally sedimented flexible film shows a double lithium storage capacity compared to the conventional vacuum-filtered MXene film, along with improved rate performance and excellent cycle stability.
Databáze: Directory of Open Access Journals
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