| Autor: |
Anna-Liis Remmel, Sander Ratso, Kerli Liivand, Mati Danilson, Kätlin Kaare, Valdek Mikli, Ivar Kruusenberg |
| Jazyk: |
angličtina |
| Rok vydání: |
2024 |
| Předmět: |
|
| Zdroj: |
Electrochemistry Communications, Vol 166, Iss , Pp 107781- (2024) |
| Druh dokumentu: |
article |
| ISSN: |
1388-2481 |
| DOI: |
10.1016/j.elecom.2024.107781 |
| Popis: |
The implementation of a technology capable of capturing and converting CO2 into valuable products is one of the key requirements for limiting the effects of our carbon-intensive industries. At the same time, future CO2 emissions need to be reduced to combat climate change, meaning that new devices capable of storing and converting energy without CO2 emissions have to be adopted widely. In this work, we demonstrate catalysts made directly from CO2 for fuel cells and zinc-air batteries. The molten salt electrolysis process is used to electrodeposit solid carbon from CO2 in two mixtures, a known eutectic mixture of Li2CO3, Na2CO3, K2CO3 and a new mixture containing 0.1 mol of LiOH in addition. The effects of the electrolyte towards the final carbon product and its electrocatalytic activity are analysed using the rotating disk electrode method, X-ray diffraction, X-ray photoelectron spectroscopy, and scanning electron microscopy. The porosity of the materials is described by N2 adsorption and the best performing catalyst is compared to the activity of a commercial 20 wt% PtRu/C material in a zinc-air battery. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
|
Full Text from ScienceDirect