Supramolecular Interactions of Terpyridine-Derived Cores of Metallomesogen Precursors
| Autor: | Yang Kim, Kil Sik Min, Shinya Hayami, Elisabeth Rukmini, Mi Seon Won, Jack M. Harrowfield, Jong Won Shin, Young Hoon Lee |
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| Jazyk: | angličtina |
| Rok vydání: | 2013 |
| Předmět: | |
| Zdroj: | International Journal of Molecular Sciences, Vol 14, Iss 10, Pp 20729-20743 (2013) |
| Druh dokumentu: | article |
| ISSN: | 14102072 1422-0067 |
| DOI: | 10.3390/ijms141020729 |
| Popis: | Use of Hirshfeld surfaces calculated from crystal structure determinations on various transition metal ion complexes of three terpyridine ligands carrying trimethoxyphenyl substituents has enabled an assessment of the contribution made by the ligand components to the interactions determining the lattice structures, interactions expected also to be present in metallomesogens derived from similar ligands. The form of the link joining the trimethoxyphenyl substituent to the 4' position of 2,2';6',2''-terpyridine is of some importance. In the case of the Co(II) complexes of two of the ligands, their spin-crossover characteristics can be rationalised in terms of the different interactions seen in their lattices. |
| Databáze: | Directory of Open Access Journals |
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