Poly[aqua(μ3-5-azaniumylisophthalato)(μ-oxalato)neodymium(III)]
| Autor: | Jun Fan, Tian-Tian Xiao, Xia Yin, Wei-Guang Zhang, Sheng-Run Zheng |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2012 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 68, Iss 5, Pp m537-m537 (2012) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536812013554 |
| Popis: | The title compound, [Nd(C8H6NO4)(C2O4)(H2O)]n, is a layer-like coordination polymer. The NdIII ion is coordinated by four carboxylate O atoms from three bridging 5-azaniumylisophthalate (Haip) ligands, four carboxylate O atoms from two oxalate (ox) anions and one ligated water molecule in a tricapped trigonal–prismatic geometry. The Haip anion acts as a μ3-bridge, connecting three NdIII ions through two carboxylate groups; the ox anion adopts a bis-bidentate-bridging mode, linking two NdIII ions. The layer framework is further extended to a three-dimensional supramolecular structure through N—H...O and O—H...O hydrogen bonds. |
| Databáze: | Directory of Open Access Journals |
| Externí odkaz: |
|