A model of chronoamperometry of a two electrons electro-deposition reaction with the adsorption of intermediate

Autor:	Milivoj Lovrić
Jazyk:	angličtina
Rok vydání:	2023
Předmět:	Two steps electrode mechanisms adsorption of intermediate logarithmic analysis simultaneous electrons transfer theory of electro-deposition reactions Chemistry QD1-999
Zdroj:	Journal of Electrochemical Science and Engineering (2023)
Druh dokumentu:	article
ISSN:	1847-9286
DOI:	10.5599/jese.2026
Popis:	A single step chronoamperometry of reversible reactions complicated by the intermediate adsorption and the product deposition on inert electrodes is compared theoretically with an initial state of a simple two electrons electro-deposition. If the intermediate is highly unstable, these two mechanisms are similar, but the mechanism with successive electron transfers is needed to explain the responses appearing generally. The stability of intermediate depends on standard potentials of two steps and on the strength of adsorption. Two limiting cases are analysed and the difference between them is described.
Databáze:	Directory of Open Access Journals
Externí odkaz:	https://doaj.org/article/5ebc8867661d411d8ed48bb2fdca0492 Zobrazit plný text záznamu View record in DOAJ