Identification of a prismatic P3N3 molecule formed from electron irradiated phosphine-nitrogen ices

Autor: Cheng Zhu, André K. Eckhardt, Sankhabrata Chandra, Andrew M. Turner, Peter R. Schreiner, Ralf I. Kaiser
Jazyk: angličtina
Rok vydání: 2021
Předmět:
Zdroj: Nature Communications, Vol 12, Iss 1, Pp 1-7 (2021)
Druh dokumentu: article
ISSN: 2041-1723
DOI: 10.1038/s41467-021-25775-1
Popis: High-nitrogen content polyhedral molecules are of fundamental interest for theory and for synthesis applications. The authors, using isomer selective, tunable soft photoionization reflectron time-of-flight mass spectrometry, identify the formation of a hitherto elusive prismatic P3N3 molecule during sublimation of PH3 and N2 ice mixtures exposed to energetic electrons.
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