| Autor: |
Domingo Salazar-Mendoza, José Luis García-Gutiérrez, Federico Jiménez-Cruz |
| Jazyk: |
angličtina |
| Rok vydání: |
2023 |
| Předmět: |
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| Zdroj: |
Arabian Journal of Chemistry, Vol 16, Iss 7, Pp 104843- (2023) |
| Druh dokumentu: |
article |
| ISSN: |
1878-5352 |
| DOI: |
10.1016/j.arabjc.2023.104843 |
| Popis: |
Structural supramolecular architectures in the solid state of 1,5-diketone malonates 1a-g are proposed to construct a small library of hydrogen bonds by C–H⋯O interactions by crystal structure analysis. A possible route of crystallization mechanism at different levels of hierarchy considers the next strategic steps: a) Intramolecular interactions provide a kite-like molecular conformation. b) Intermolecular interactions provide molecular recognition between the structural unit, synthon, and macrocycles. c) The supramolecular architectures obtained from the conjunction of the multiple functions performed by the C–H⋯O interactions. X-ray studies and Hirshfeld Surface Analysis are described. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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