Dicarbonyldichloridobis(trimethylphosphane)iron(II)–carbonyldichloridotris(trimethylphosphane)iron(II)–tetrahydrofuran (1/1/2)
| Autor: | Nigam P. Rath, Meghan Stouffer, Matthew K. Janssen, John R. Bleeke |
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| Jazyk: | angličtina |
| Rok vydání: | 2011 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 67, Iss 4, Pp m462-m462 (2011) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536811009305 |
| Popis: | The asymmetric unit of the title crystal, [FeCl2(C3H9P)3(CO)]·[FeCl2(C3H9P)2(CO)2]·2C4H8O, contains half molecules of the two closely related FeII complexes lying on mirror planes and a tetrahydrofuran solvent molecule, one C atom of which is disordered over two sets of sites with site occupancy factors 0.633 (9) and 0.367 (9). In both FeII complex molecules, a distorted octahedral coordination geometry has been observed around the Fe atoms. Weak intermolecular C—H...O interactions are observed in the crystal structure. |
| Databáze: | Directory of Open Access Journals |
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