Crystal structure and catalytic activity of tetrakis(μ2-ethyl 2,6-di-tert-butyl-4-methylphenyl phosphato-κ2O:O′)bis(ethyl 2,6-di-tert-butyl-4-methylphenyl phosphato-κ2O,O′)dilutetium n-heptane disolvate
| Autor: | Mikhail E. Minyaev, Alexander N. Tavtorkin, Sof'ya A. Korchagina, Ilya E. Nifant'ev, Andrei V. Churakov |
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| Jazyk: | angličtina |
| Rok vydání: | 2018 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E: Crystallographic Communications, Vol 74, Iss 4, Pp 543-547 (2018) |
| Druh dokumentu: | article |
| ISSN: | 2056-9890 20569890 |
| DOI: | 10.1107/S2056989018004565 |
| Popis: | The title complex, [Lu2(C17H28O4P)6]·2C7H16, was formed in the reaction between potassium 2,6-di-tert-butyl-4-methylphenyl ethyl phosphate, [K(2,6-tBu2-4-MeC6H2-O)(EtO)PO2], and LuCl3(H2O)6 in water, followed by vacuum drying and recrystallization from heptane. Its crystal structure has triclinic (P\overline{1}) symmetry at 120 K. The lutetium tris(phosphate) complex has a binuclear [Lu2(μ-OPO)4] core and the organophosphate ligand exhibits κ2O,O′ terminal and μ2-κ1O:κ1O′ bridging coordination modes with the LuIII ion being sixfold coordinated. The complex is of interest as a precatalyst in the acrylonitrile polymerization process and displays good catalytic activity under mild conditions. |
| Databáze: | Directory of Open Access Journals |
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