Mid-IR Optical Property of Dy:CaF2-SrF2 Crystal Fabricated by Multicrucible Temperature Gradient Technology

Autor: Lihe Zheng, Jianbin Zhao, Yangxiao Wang, Weichao Chen, Fangfang Ruan, Hui Lin, Yanyan Xue, Jian Liu, Yang Liu, Ruiqin Yang, Haifeng Lu, Xiaodong Xu, Liangbi Su
Jazyk: angličtina
Rok vydání: 2021
Předmět:
Zdroj: Crystals, Vol 11, Iss 8, p 907 (2021)
Druh dokumentu: article
ISSN: 2073-4352
DOI: 10.3390/cryst11080907
Popis: Dy3+-doped CaF2-SrF2 crystals with various Dy3+ dopant concentrations were synthesized by multicrucible temperature gradient technology (MC-TGT). Dy:CaF2-SrF2 crystals were fluorite structured and crystallized in cubic Fm3¯m space group, as characterized by X-ray diffraction. The crystallographic site concentration was calculated from the measured density by Archimedes’ hydrostatic weighing principle. The optical transmission reached over 90% with a sample thickness of 1.0 mm. The Sellmeier dispersion formula was obtained following the measured refractive index in a mid-IR range of 1.7–11 μm. Absorption coefficients of 6.06 cm−1 and 12.71 cm−1 were obtained at 804 nm and 1094 nm in 15% Dy:CaF2-SrF2 crystal. The fluorescence spectra of 15 at.% Dy:CaF2-SrF2 showed the strongest wavelength peak at 2919 nm with a full width at half maximum (FWHM) of 267 nm under an excitation wavelength of 808 nm. The fluorescence lifetimes were illustrated for different Dy3+ dopant levels of 5%, 10% and 15%. The results indicate that the Dy:CaF2-SrF2 crystal is a promising candidate for compact mid-IR lasers.
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