Determinação espectrofotométrica em fluxo de cloro em água usando célula de longo caminho óptico e multicomutação Spectrophotometric flow determination of chlorine in water using a long pathlength optic cell and multicommutation

Autor: Fernanda Helena Salami, Viviane Gomes Bonifácio, Orlando Fatibello-Filho, Luiz Humberto Marcolino-Jr
Jazyk: English<br />Spanish; Castilian<br />Portuguese
Rok vydání: 2009
Předmět:
Zdroj: Química Nova, Vol 32, Iss 1, Pp 112-115 (2009)
Druh dokumentu: article
ISSN: 0100-4042
1678-7064
DOI: 10.1590/S0100-40422009000100021
Popis: A multicommuted method for determination of chlorine in water samples using a 100-cm cell was developed. In this method, orto-Tolidine reacts with chlorine and the product was monitored at 438 nm. The analytical curve for chlorine was linear in concentration range from 1.34x10-6 to 2.01x10-5 mol L-1 with a detection limit of 9.40x10-8 mol L-1. A sampling rate of 45 h-1and a RSD of 1.0 % (n = 15) were obtained. The method was applied with success for chlorine determination in six water samples.
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