Improved corrosion resistance of TiAlCrNbMo alloy to lead-bismuth eutectic by pre-oxidation

Autor: Y. Liu, H.E. Ge, Q.S. Ren, H.W. Deng, Z. Li, B. Du, T. Zhang
Jazyk: angličtina
Rok vydání: 2024
Předmět:
Zdroj: Journal of Materials Research and Technology, Vol 28, Iss , Pp 707-718 (2024)
Druh dokumentu: article
ISSN: 2238-7854
DOI: 10.1016/j.jmrt.2023.12.044
Popis: A Ti48.5Al46Cr3Nb0.5Mo2 alloy was designed and fabricated to investigate its corrosion resistance to static liquid lead-bismuth eutectic (LBE). The microstructure and corrosion behavior of un-oxidized and pre-oxidized samples were compared. The results show that LBE preferentially penetrated into the alloy along the CrMo-rich σ phase formed at high-temperature. A TiO2 and Al2O3 oxide layer was formed on the surface of the matrix after 2 h pre-oxidized leading to remarkable LBE resistance. When extended the pre-oxidized time to 4 h, the exfoliation of the oxide layer caused by the evaporation of MoO3 significantly weakens the corrosion resistance.
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