Selective Double Addition Reaction of an E‒H Bond (E = Si, B) to a C≡N Triple Bond of Organonitriles

Autor:	Masumi Itazaki, Hiroshi Nakazawa
Jazyk:	angličtina
Rok vydání:	2018
Předmět:	hydrosilylation hydroborylation dihydroborylsilylation Organic chemistry QD241-441
Zdroj:	Molecules, Vol 23, Iss 11, p 2769 (2018)
Druh dokumentu:	article
ISSN:	1420-3049
DOI:	10.3390/molecules23112769
Popis:	The catalytic double hydrometalation such as hydrosilylation and hydroborylation of organonitriles has attracted considerable attention because the obtained products are widely used in organic synthesis and it is thought to be one of the effective methods for reduction of organonitriles. However, the examples of these reactions are quite limited to date. This paper summarizes the development of selective double hydrosilylation, double hydroborylation, and dihydroborylsilylation of organonitriles, including their reaction mechanisms and the role of the metal species in the catalytic cycle.
Databáze:	Directory of Open Access Journals
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