| Autor: |
Nada Glumac, Milan Momčilović, Iztok Kramberger, Darko Štraus, Nikola Sakač, Elvira Kovač-Andrić, Bojan Đurin, Marija Kraševac Sakač, Kristina Đambić, Marija Jozanović |
| Jazyk: |
angličtina |
| Rok vydání: |
2024 |
| Předmět: |
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| Zdroj: |
Sensors, Vol 24, Iss 8, p 2388 (2024) |
| Druh dokumentu: |
article |
| ISSN: |
1424-8220 |
| DOI: |
10.3390/s24082388 |
| Popis: |
Two new surfactant sensors were developed by synthesizing Pt-doped acid-activated multi-walled carbon nanotubes (Pt@MWCNTs). Two different ionophores using Pt@MWCNTs, a new plasticizer, and (a) cationic surfactant 1,3-dihexadecyl-1H-benzo[d]imidazol-3-ium-DHBI (Pt@MWCNT-DHBI ionophore) and (b) anionic surfactant dodecylbenzenesulfonate-DBS (Pt@MWCNT-DBS ionophore) composites were successfully synthesized and characterized. Both surfactant sensors showed a response to anionic surfactants (dodecylsulfate (SDS) and DBS) and cationic surfactants (cetylpyridinium chloride (CPC) and hexadecyltrimethylammonium bromide (CTAB)). The Pt@MWCNT-DBS sensor showed lower sensitivity than expected with the sub-Nernstian response of ≈23 mV/decade of activity for CPC and CTAB and ≈33 mV/decade of activity for SDS and DBS. The Pt@MWCNT-DHBI surfactant sensor had superior response properties, including a Nernstian response to SDS (59.1 mV/decade) and a near-Nernstian response to DBS (57.5 mV/decade), with linear response regions for both anionic surfactants down to ≈2 × 10−6 M. The Pt@MWCNT-DHBI was also useful in critical micellar concentration (CMC) detection. Common anions showed very low interferences with the sensor. The sensor was successfully employed for the potentiometric titration of a technical grade cationic surfactant with good recoveries. The content of cationic surfactants was measured in six samples of complex commercial detergents. The Pt@MWCNT-DHBI surfactant sensor showed good agreement with the ISE surfactant sensor and classical two-phase titration and could be used as an analytical tool in quality control. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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