Synthesis and structural characterization of β -cyclodextrin butenate

Autor:	Yong-Fu Li, Zhu-Xi Tian, Bin Shi, Yang-Bo He, Ming-Xiu Long
Jazyk:	angličtina
Rok vydání:	2023
Předmět:	β-cyclodextrin β-cyclodextrin butenate n n’-carbonyldiimidazole esterification Polymers and polymer manufacture TP1080-1185
Zdroj:	Designed Monomers and Polymers, Vol 26, Iss 1, Pp 132-139 (2023)
Druh dokumentu:	article
ISSN:	1385-772X 1568-5551 15685551 41132904
DOI:	10.1080/15685551.2023.2205741
Popis:	β-cyclodextrin butenate was synthesized by using N, N’-Carbonyldiimidazole (CDI) activating reagent and 4-Dimethylaminopyridine (DMAP) as catalyst. The best preparation condition of β-CD butenate was described as below: reaction temperature was 25°C, concentration of 2-butenoic acid was 450 mmol/L, concentration of DMAP was 12.5 mmol/L and reaction time was 20 minutes and at this condition the yield of β-CD butenate was 0.83 mmol/g. According to the results of FT-IR spectrum, NMR spectroscopy and HPLC-QTof-mass spectrum of β-CD butenate, there were four types β-CD butenate synthesized, which were β-CD-2-butenoic acid monoester, β-CD-2-butenoic acid diester, β-CD-2-butenoic acid triester and β-CD-2-butenoic acid tetraester, respectively.
Databáze:	Directory of Open Access Journals
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