Ethyl [(2-hydroxyphenyl)(pyridinium-2-ylamino)methyl]phosphonate methanol solvate

Autor: Ming-Xia Li, Miao-Li Zhu, Li-Ping Lu
Jazyk: angličtina
Rok vydání: 2008
Předmět:
Zdroj: Acta Crystallographica Section E, Vol 64, Iss 7, Pp o1178-o1179 (2008)
Druh dokumentu: article
ISSN: 16005368
1600-5368
DOI: 10.1107/S1600536808015675
Popis: In the title compound, C14H17N2O4P·CH3OH, the planes of the pyridinium-2-ylamino and 2-hydroxyphenyl groups form a dihedral angle of 75.6 (1)°, with the pyridinium NH group and the 2-hydroxyphenyl OH group pointing in opposite directions. Three intramolecular hydrogen bonds are observed. Two phosphonate and two methanol molecules are connected by O—H...O hydrogen bonds as a centrosymmetric dimeric cluster, and interact further with other dimeric clusters via N—H...O, O—H...O and C—H...O hydrogen bonds and C—H...π interactions, resulting in a sheet structure.
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