| Autor: |
Yohei Haketa, Yuya Bando, Yoshifumi Sasano, Hiroki Tanaka, Nobuhiro Yasuda, Ichiro Hisaki, Hiromitsu Maeda |
| Jazyk: |
angličtina |
| Rok vydání: |
2019 |
| Předmět: |
|
| Zdroj: |
iScience, Vol 14, Iss , Pp 241-256 (2019) |
| Druh dokumentu: |
article |
| ISSN: |
2589-0042 |
| DOI: |
10.1016/j.isci.2019.03.027 |
| Popis: |
Summary: Porphyrin–AuIII complexes were found to act as π-electronic cations, which can combine with various counteranions, including π-electronic anions. Single-crystal X-ray analyses revealed the formation of assemblies with contributions of charge-by-charge and charge-segregated assemblies, depending on the geometry and electronic state of the counteranions. Porphyrin–AuIII complexes possessing aliphatic alkyl chains formed dimension-controlled ion-pairing assemblies as thermotropic liquid crystals, whose ionic components were highly organized by π–π stacking and electrostatic interactions. : Chemistry; Supramolecular Chemistry; Electronic Materials Subject Areas: Chemistry, Supramolecular Chemistry, Electronic Materials |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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