Highly intensive emission of the NV− centers in synthetic HPHT microdiamonds at low nitrogen doping

Autor: K. V. Bogdanov, M. V. Zhukovskaya, V. Yu. Osipov, E. V. Ushakova, M. A. Baranov, K. Takai, A. Rampersaud, A. V. Baranov
Jazyk: angličtina
Rok vydání: 2018
Předmět:
Zdroj: APL Materials, Vol 6, Iss 8, Pp 086104-086104-8 (2018)
Druh dokumentu: article
ISSN: 2166-532X
DOI: 10.1063/1.5045535
Popis: Synthetic high-pressure high-temperature (HPHT) microdiamonds demonstrate strong resonant-like enhancement of the NV− photoluminescence (PL) at unexpectedly low concentration of the substitutional nitrogen atoms (NS) of 90 ppm, which is significantly smaller than the ∼250 ppm characteristic for conventional HPHT synthesis. The EPR, Raman, and luminescent spectroscopies, including time-resolved PL, provide evidence that this is due to competition between the increase in PL with increasing concentration of the NV− centers and nonradiative deactivation of these centers by defects induced by the NS in the diamond crystal lattice. It is suggested that the intensity of the NV− center emission can be optimized by the appropriate choice of nitrogen doping concentration which does not substantially disrupt the diamond crystal lattice.
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