Thermal decomposition of vinyl- and allylsilane platinum(II) complexes and platinum(II) catalysed synthesis of (E),(E)-1,4-diphenyl-1,3-butadiene
| Autor: | Paul P. Mebe, John W. Fitch, Mark Munyai |
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| Jazyk: | angličtina |
| Rok vydání: | 2008 |
| Předmět: | |
| Zdroj: | Bulletin of the Chemical Society of Ethiopia, Vol 22, Iss 3, Pp 445-448 (2008) |
| Druh dokumentu: | article |
| ISSN: | 1011-3924 1726-801X |
| Popis: | Thermal stabilities of Pt(II) complexes: K[PtCl3(CH2=CHSiMe3)], K[PtCl3(CH2=CHCH2SiMe3)], K[(acac)PtCl(CH2=CHSiMe3)] and [PtCl(CH2=CHCH2SiMe3)]2, were examined. All complexes were found to be stable at room temperature but they decomposed without melting above about 90 oC. The allylsilane complex decomposed above about 125 oE),(E)-1,4-diphenyl-1,3-butadiene was stereoselectively synthesised in good yield from (E)-β-styrylsilane in the presence of Zeise’s salt. |
| Databáze: | Directory of Open Access Journals |
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