Local lattice distortions and chemical short-range order in MoNbTaW
| Autor: | Andrea Fantin, Anna Maria Manzoni, Hauke Springer, Reza Darvishi Kamachali, Robert Maaß |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2024 |
| Předmět: | |
| Zdroj: | Materials Research Letters, Vol 12, Iss 5, Pp 346-354 (2024) |
| Druh dokumentu: | article |
| ISSN: | 21663831 2166-3831 |
| DOI: | 10.1080/21663831.2024.2326014 |
| Popis: | Extended X-ray absorption fine structure (EXAFS) conducted on an equiatomic MoNbTaW bcc medium-entropy alloy that was annealed at 2273 K reveals unexpectedly small 1st and 2nd shell element-specific lattice distortions. An experimental size-mismatch parameter, [Formula: see text], is determined to be ca. 50% lower than the corresponding calculated value. Around W, short-range order (SRO) preferring 4d elements in the 1st and 2nd shells persists. A Nb-W ordering is found, which is reminiscent of ordering emerging at lower temperatures in the B2(Mo,W;Ta,Nb)- and B32(Nb,W)-phases. With high-temperature ordering preferences in fcc also foreshadowing low-temperature phase, these findings suggest a general feature of high-temperature SRO. |
| Databáze: | Directory of Open Access Journals |
| Externí odkaz: |
|