Evidence for ligand- and solvent-induced disproportionation of uranium(IV)

Autor: Jingzhen Du, Iskander Douair, Erli Lu, John A. Seed, Floriana Tuna, Ashley J. Wooles, Laurent Maron, Stephen T. Liddle
Jazyk: angličtina
Rok vydání: 2021
Předmět:
Zdroj: Nature Communications, Vol 12, Iss 1, Pp 1-12 (2021)
Druh dokumentu: article
ISSN: 2041-1723
DOI: 10.1038/s41467-021-25151-z
Popis: Disproportion of uranium(IV) is rare, as it is usually the stable product of uranium(III) or (V) disproportionation. Here, the authors report uranium(IV) disproportionation to uranium(III) and (V) revealing ligand and solvent control over a key thermodynamic property of uranium
Databáze: Directory of Open Access Journals