2,2′-Iminodiethanaminium 2,2′-(disulfanyldiyl)dibenzoate dihydrate
| Autor: | Grant A. Broker, Edward R. T. Tiekink |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2010 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 66, Iss 3, Pp o718-o718 (2010) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536810007117 |
| Popis: | In the title hydrated salt, C4H15N32+·C14H8O4S2−·2H2O, the dication (with both terminal –NH2 groups protonated) adopts a U-shaped conformation, the Namine—C—C—Nazanium torsion angles being 57.9 (6) and 60.3 (6)°. The dianion is twisted: the central C—S—S—C torsion angle is 81.3 (2)° and the dihedral angle between the benzene rings is 85.4 (3)°. In the crystal, a chain in the a-axis direction mediated by water–carboxylate O—H...O hydrogen bonds through a sequence of alternating 12-membered {...OCO...HOH}2 and eight-membered {...O...HOH}2 synthons occurs, which involves only one of the carboxylate residues. The second carboxylate residue participates in N—H...O hydrogen bonding, generating a three-dimensional network, along with azanium–water N—H...O hydrogen bonds. |
| Databáze: | Directory of Open Access Journals |
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