Crystal structure of bis[(η5-tert-butylcyclopentadienyl)tricarbonylmolybdenum(I)](Mo—Mo)

Autor:	Nigar Z. Ibrahimova, Dilgam B. Tagiyev, Iltifat U. Lyatifov, Mehmet Akkurt, Khudayar I. Hasanov, Ajaya Bhattarai
Jazyk:	angličtina
Rok vydání:	2024
Předmět:	crystal structure mo complex carbonyl ligands cyclopentadienyl ligand tert-butyl group carbonyl group binuclear complex steric effect Crystallography QD901-999
Zdroj:	Acta Crystallographica Section E: Crystallographic Communications, Vol 80, Iss 8, Pp 882-885 (2024)
Druh dokumentu:	article
ISSN:	2056-9890 20569890
DOI:	10.1107/S2056989024006959
Popis:	The dinuclear molecule of the title compound, [Mo2(C9H13)2(CO)6] or [Mo(tBuCp)(CO)3]2 where tBu and Cp are tert-butyl and cyclopentadienyl, is centrosymmetric and is characterized by an Mo—Mo bond length of 3.2323 (3) Å. Imposed by inversion symmetry, the tBuCp and the carbonyl ligands are in a transoid arrangement to each other. In the crystal, intermolecular C—H...O contacts lead to the formation of layers parallel to the bc plane.
Databáze:	Directory of Open Access Journals
Externí odkaz:	https://doaj.org/article/5a452b8867b149eebfa38713aa3630be Zobrazit plný text záznamu View record in DOAJ