Autor: |
Dongfu Song, Yuliang Zhao, Yiwang Jia, Xintao Li, Yanan Fu, Weiwen Zhang |
Jazyk: |
angličtina |
Rok vydání: |
2023 |
Předmět: |
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Zdroj: |
Journal of Materials Research and Technology, Vol 24, Iss , Pp 527-541 (2023) |
Druh dokumentu: |
article |
ISSN: |
2238-7854 |
DOI: |
10.1016/j.jmrt.2023.03.045 |
Popis: |
Individual manganese (Mn) modification cannot prevent the formation of coarse and blocky Iron-rich phases in recycled Al–Si alloys. In the present work, scanning/transmission electron microscopy (SEM/TEM), thermodynamic calculations, and synchrotron X-ray imaging were comprehensively applied to reveal the synergistic effect of Mn and B (boron) on Iron-rich phase formation in Al–Si–Fe alloys during solidification. The results showed that with addition of Mn and B, the morphology of Iron-rich phase translated from the coarse primary into a uniform and hollow-shaped multibranched Chinese-script morphology. An appropriate boron amount significantly reduced the initial nucleation temperature of the primary Iron-rich phase and increased the number of nucleation cites. The TEM results show that there was no obvious orientations relationship between the AlB2 and α-Al15(MnFe)3Si2 phases. The main modification mechanism is that B was adsorbed on the oxide film surface, which hindered the formation of the Iron-rich phase at high temperature. This Mn + B compound modification method provides an alternative way to enhance the mechanical properties of recycled Al–Si alloys in industry. |
Databáze: |
Directory of Open Access Journals |
Externí odkaz: |
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