| Autor: |
Yi-Ying Chin, Hong-Ji Lin, Zhiwei Hu, Chang-Yang Kuo, Daria Mikhailova, Jenn-Min Lee, Shu-Chih Haw, Shin-An Chen, Walter Schnelle, Hirofumi Ishii, Nozomu Hiraoka, Yen-Fa Liao, Ku-Ding Tsuei, Arata Tanaka, Liu Hao Tjeng, Chien-Te Chen, Jin-Ming Chen |
| Jazyk: |
angličtina |
| Rok vydání: |
2017 |
| Předmět: |
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| Zdroj: |
Scientific Reports, Vol 7, Iss 1, Pp 1-9 (2017) |
| Druh dokumentu: |
article |
| ISSN: |
2045-2322 |
| DOI: |
10.1038/s41598-017-03950-z |
| Popis: |
Abstract The pressure-response of the Co-O bond lengths and the spin state of Co ions in a hybrid 3d-5d solid-state oxide Sr2Co0.5Ir0.5O4 with a layered K2NiF4-type structure was studied by using hard X-ray absorption and emission spectroscopies. The Co-K and the Ir-L 3 X-ray absorption spectra demonstrate that the Ir5+ and the Co3+ valence states at ambient conditions are not affected by pressure. The Co Kβ emission spectra, on the other hand, revealed a gradual spin state transition of Co3+ ions from a high-spin (S = 2) state at ambient pressure to a complete low-spin state (S = 0) at 40 GPa without crossing the intermediate spin state (S = 1). This can be well understood from our calculated phase diagram in which we consider the energies of the low spin, intermediate spin and high spin states of Co3+ ions as a function of the anisotropic distortion of the octahedral local coordination in the layered oxide. We infer that a short in-plane Co-O bond length ( |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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