Aquabis(triphenylphosphine-κP)copper(I) tetrafluoridoborate
| Autor: | Yanfeng Dai, Yi Zhang, Jianwen Tian, Zhen Liu |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2009 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 65, Iss 8, Pp m1001-m1001 (2009) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536809029559 |
| Popis: | In the title compound, [Cu(C18H15P)2(H2O)]BF4, the CuI atom is coordinated by two P atoms from triphenylphosphine ligands and one water molecule in a distorted trigonal geometry. In the BF4− anion, three F atoms are disordered over two sites around the B—F bond, the site-occupancy ratio being 0.67 (6):0.33 (6). The Cu...F distance of 2.602 (5) Å between the Cu atom and the ordered F atom may suggest a weak but genuine interaction. O—H...F and weak C—H...F hydrogen bonding is present in the crystal structure. |
| Databáze: | Directory of Open Access Journals |
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