| Autor: |
Xiuzheng Li, Jun Liao, Xiaobin Zhuo, Huamin Wang, Xiaoyun Chai, Yan Zou, Qingjie Zhao |
| Jazyk: |
angličtina |
| Rok vydání: |
2023 |
| Předmět: |
|
| Zdroj: |
Green Synthesis and Catalysis, Vol 4, Iss 1, Pp 54-57 (2023) |
| Druh dokumentu: |
article |
| ISSN: |
2666-5549 |
| DOI: |
10.1016/j.gresc.2022.10.015 |
| Popis: |
A highly efficient and mild method for [3 + 2] cycloaddition of β-sulfonyl-α,β-unsaturated ketones with terminal allenoates was well-explored and developed. The reactions were successfully performed by applying multifunctional chiral phosphine P6 which was screened from eight chiral phosphorus reagents to finally result in a variety of enantioenriched sulfone-substituted cyclopentenes with two chiral centers (up to 81% yield with 94% ee). Moreover, 2.5 mol% catalytic equivalents were proved to be feasible when this reaction was performed on a 10 mmol scale. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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